4-Anilino-3-nitro-N-phenylbenzamide

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4-Anilino-3-nitro-N-phenyl­benzamide

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In the title moleclue, C(13)H(10)N(4)O(3), the methyl-idene-hydrazide [-C(=O)-N-N=C-] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the methyl-idene-hydrazide fragment. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds l...

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In the mol-ecule of the title compound, C(12)H(16)N(2)O(4), an intra-molecular N-H⋯O hydrogen bond results in the formation of a six-membered ring having an envelope conformation. In the crystal structure, a bifurcated intra/intermolecular N-H⋯(O,O) hydrogen bond generates inversion dimers.

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The title compound, C(14)H(10)N(4)O(5), has an E conformation with respect to the C=N bond. The dihedral angle between the benzene rings is 2.41 (14)°. In the crystal, mol-ecules are linked through N-H⋯O hydrogen bonds to form chains along the c axis. C-H⋯O inter-actions are also present, linking the chains to form a three-dimensional network.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810043849